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Desizing process reactions - Hydrolytic and Oxidation method

Hydrolytic and Oxidation method

Desizing process
Desizing process

In desizing process, to convert starch into glucose, there are two ways as follows-

Two types of methods are made on two types of reactions during Desizing -

(A) Hydrolytic method. 

(B) Oxidation Method 

These two types of reactions convert starch into alpha glucose.


Hydrolytic method

Chemically, starch is a mixture of amylose straight chains and amylopectin branching chains that are insoluble in water. 

They can be rendered soluble by hydrolysis, which produces an Alpha glucose unit that is soluble in water.

Hydrolytic method for desizing
Hydrolytic method

Oxidative method 

With the help of nascent oxygen (O), starch is oxidized and transformed into Dextrin. 

Under ideal chemical and temperature circumstances, oxidizing agents liberate nascent oxygen, which aids in the oxidation of starch into a water-soluble state.

Strong oxidizing agents should be used which give nascent oxygen.

Ex. KMnO4, NaOCL, H2O2, Sodium bromite, etc.

Advantages

Disadvantage-

This method is suitable for blend composition.

If conditions are not followed then oxycellulose formation takes place which hampers the fabric.

Excellent & uniform removal of size.

Machine corrosion takes place.

Energy & water consumption is less.

The process is costly.

It can be combined with preparatory processes like scouring, bleaching, etc.

Working with chemicals is harmful to the human body.


Oxidative method for desizing process
Oxidative method for desizing process
Oxidative method for desizing process
Oxidative method for desizing process

Questions -

  1. What are the two methods of desizing reactions?
  2. Describe hydrolytic method for desizing with its reactions.
  3. Describe oxidation method for desizing process with its reactions.

References

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Arputharaj, A., Raja, A. S. M., & Saxena, S. (2016). Developments in sustainable chemical processing of textiles. In Green Fashion (pp. 217–252). Springer Singapore.

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Chemicals used in textile processing. (2013, January 10). OEcotextiles. https://oecotextiles.blog/2013/01/10/chemicals-used-in-textile-processing/

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Get to know about chemical processing of textile materials. (2022, May 10). ECHEMI. https://www.echemi.com/cms/640314.html

Kan, C.-W. (2015). Plasma treatments for sustainable textile processing. In Sustainable Apparel (pp. 49–118). Elsevier.

Textile School. (2010, November 10). Fabric wet processing techniques. Textile School. https://www.textileschool.com/343/fabric-wet-processing-techniques/

textileblog. (2020, June 19). Stages of wet processing in textile industry. Textile Blog. https://www.textileblog.com/stages-of-wet-processing-in-textile-industry/

Vigo, T. L. (2014). Textile processing and properties: Preparation, dyeing, finishing and performance: Preparation, dyeing, finishing and performance (1st ed.). Elsevier Science & Technology. https://www.elsevier.com/books/textile-processing-and-properties/vigo/978-0-444-88224-0?country=GB&format=print&utm_source=google_ads&utm_medium=paid_search&utm_campaign=ukshopping&gclid=CjwKCAiAhqCdBhB0EiwAH8M_Gn3kr_d2paqVzccxckWobOsLcwl0cD_Mu6vA5I-eqFARiZwx32eUOxoC-LMQAvD_BwE&gclsrc=aw.ds

(N.d.). Textilelearner.net. https://textilelearner.net/flow-chart-of-textile-wet-processing/

Babu, S. (n.d.). Textile Adviser. Textileadvisor.com. from https://www.textileadvisor.com/2021/12/fabric-desizing-process-types-of.html

Desizing. (n.d.). Kemin. from https://www.garmonchemicals.com/en/textile-chemicals/garment-denim-finishing/enzyme-desizing

Landage, S. M. (2022). Biotechnological approaches in desizing of textile materials. In O. L. Shanmugasundaram (Ed.), Applications of Biotechnology for Sustainable Textile Production (pp. 47–73). Elsevier.

Madhu, C. (n.d.). TEXTILE CHEMROSE. Blogspot.com. from https://textilechemrose.blogspot.com/2015/12/desizing.html

Process of cotton Textile Materials desizing. (2013, September 12). Fibre2fashion.com; Fibre2Fashion. https://www.fibre2fashion.com/industry-article/7064/problems-in-desizing-cotton-textile-materials

Trivedi, Y. (2021, May 9). Textile Desizing process. Textilesphere.com. https://www.textilesphere.com/2021/05/desizing-textile.html


Further reading,


Writer
 - Rushikesh Patil (Textile Engineer)
(DKTE Society textile engineering college Ichalkaranji)
Email Id - rushikeshpatil23052002@gmail.com

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